Faculty of Engineering & Technology

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Browsing Faculty of Engineering & Technology by Author "Akach, John Willis Juma Pesa"

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    Hybrid light photocatalysis of aromatic wastes in a fluidized bed reactor
    (Vaal University of Technology, 2022-08) Akach, John Willis Juma Pesa; Tshilenge, John Kabuba, Prof.; Aoyi, Ochieng, Prof.
    The use of solar photocatalysis for the treatment of aromatic chemicals like phenol in wastewater has attracted significant attention due to the low cost of sunlight. However, sunlight is unreliable since its intensity fluctuates during the day. This drawback can be addressed by supplementing sunlight with artificial UV lamps when the solar intensity reduces. In this work, such a hybrid solar/UV lamp reactor, internally illuminated by the UV lamp and externally by sunlight, was designed. Phenol was used as the model pollutant and the nanophase Aeroxide P25 TiO2 was employed as the photocatalyst and fluidized by compressed air. The catalyst and bubble distribution in the reactor was analysed using computational fluid dynamics (CFD) while the Monte Carlo (MC) method was used to model the light distribution and reaction kinetics. Finally, a lamp controller was designed to specify the required UV lamp output as a function of the solar intensity. The CFD simulation using ANSYS CFX 17 showed that a fairly homogeneous distribution of the catalyst was achieved in the reactor. Consequently, accurate simulations of the light distribution could be achieved without considering the hydrodynamics. The MC models revealed that bubbles did not significantly influence light absorption at the optimum catalyst loading. This showed that air was a good medium for fluidization as it could provide good mixing and oxygen electron acceptor without negatively affecting light absorption. The forward scattering behaviour of the P25 TiO2 and the increase in light attenuation with catalyst loading was confirmed in this work. The optimum catalyst loading in the different reactor configurations was 0.15 g/L (tubular solar), 0.2 g/L (annular solar), 0.4 g/L (annular UV lamp), and 0.4 g/L (hybrid light). This resulted in experimental reaction rates of 0.337 mgL-1min-1 (tubular solar), 0.584 mgL-1min-1 (annular UV lamp), and 0.93 mgL-1min-1 (hybrid light). An analysis of the local volumetric rate of energy absorption (LVREA) and reaction rate profiles along the radial coordinate showed a non-uniformity which worsened with an increase in catalyst loading. The reaction order with respect to the volumetric rate of energy absorption (VREA) indicated that solar illumination resulted in a higher electron-hole recombination as compared to UV illumination. This, combined with the higher intensity of the UV lamp, resulted in a higher reaction rate under UV light as compared to sunlight, demonstrating that the UV lamp could be used to supplement sunlight. For a typical sunny day, a lamp controller was designed that could adjust the UV lamp output as a function of the solar intensity to maintain the reaction rate at a reference level while ensuring less energy consumption than an ON/OFF lamp controller. This work demonstrated the feasibility of hybrid solar/UV lamp photocatalysis reactor which could maintain the advantages of solar photocatalysis while mitigating its drawbacks.
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    Solar photocatalytic degradation and adsorption of emerging pharmaceutical contaminants in wastewater
    (Vaal University of Technology, 2014-09-15) Akach, John Willis Juma Pesa; Onyango, Maurice S., Prof.; Aoyi, Ochieng, Prof.
    Pharmaceutical pollutants in wastewater have become an increasing concern in recent years. Adsorption and photocatalytic degradation of pharmaceutical pollutants have proved to be very efficient in the removal of pharmaceutical contaminants. In this study, a composite catalyst of powdered activated carbon (PAC) and TiO2 bound by silica xerogel (CTS composite) was synthesized and characterised using SEM, XRD and XRF. The composite catalyst was then used to adsorb and photodegrade the pharmaceuticals sulfamethoxazole (SMX), diclofenac (DCF) and carbamazepine (CBZ) in a three phase fluidised bed photocatalytic reactor using sunlight to activate the TiO2. The solar radiation intensity at the Vaal University of Technology and the hydrodynamic behaviour of the reactor were also investigated. Additionally, the effect of catalyst composition and loading, hydrodynamics and solution characteristics on the adsorption and photodegradation of the substrates was investigated. It was found that the solar radiation intensity varied with the hour of day, weather and seasons of the year. SEM showed that the porosity of the composite catalyst increased with increase in the PAC loading and a decrease in the silica xerogel loading. The XRD results showed that the silica xerogel and the PAC did not alter the composition of the P25 TiO2. XRF showed that the method used in the preparation of the substrates resulted in the desired composition of the catalyst. The optimum CTS composition was 60% silica xerogel loading and 10% PAC/TiO2 ratio. The best mass of the composite catalyst was 1.5 g/l. Using the optimal composite composition resulted in over 90% removal of the substrates with low residual solution turbidity of less than 3.5 formazin attenuation units (FAU). The optimum hydrodynamic condition was obtained when the reactor inclination angle and superficial air velocity were 75° and 0.014 m/s, respectively. However, a reactor inclination angle of 75° and a superficial velocity of 0.007 m/s gave the best adsorption and photodegradation of the substrates. Reducing the initial concentration of the substrates resulted in an increase in the efficiency of removal of the substrates. The adsorption and photodegradation of SMX was observed to increase with a decrease in pH and was maximum at pH 4. The adsorption of SMX and DCF was found to follow the Langmuir isotherm model. These results show that the use of the synthesised composite catalyst in the fluidised bed reactor provided a stable and efficient system capable of long term use. The results from this work also show that this system can be used for the removal of pharmaceutical substrates at low concentrations.